High efficiency thermally activated delayed fluorescence based on 1,3,5-tris(4-(diphenylamino)phenyl)-2,4,6-tricyanobenzene.
Identifieur interne : 000192 ( Main/Exploration ); précédent : 000191; suivant : 000193High efficiency thermally activated delayed fluorescence based on 1,3,5-tris(4-(diphenylamino)phenyl)-2,4,6-tricyanobenzene.
Auteurs : Masatsugu Taneda [Japon] ; Katsuyuki Shizu ; Hiroyuki Tanaka ; Chihaya AdachiSource :
- Chemical communications (Cambridge, England) ; 2015.
Abstract
A trigonal donor-acceptor molecule of 1,3,5-tris(4-(diphenylamino)phenyl)-2,4,6-tricyanobenzene (3DPA3CN) was synthesized to exhibit efficient thermally activated delayed fluorescence. By doping 3DPA3CN into a wide energy gap host, the film had a photoluminescence quantum efficiency of 100% with the reverse intersystem crossing efficiency of 100%. An OLED including the emitter exhibited a very high external quantum efficiency (η(EQE)) of 21.4%.
DOI: 10.1039/c5cc00511f
PubMed: 25705974
Affiliations:
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